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71.
We have conducted hydration–dehydration experiments on terrestrial olivine to investigate the behavior of oxygen isotopic fractionation to test the hypothesis that multiple cycles of aqueous and thermal processing on a parent asteroid comprise a genetic relationship between CM2s and metamorphosed carbonaceous chondrites (MCCs). Two experiments were undertaken. In the first experiment, serpentine was obtained by hydrating terrestrial olivine (Fo90.9) in the laboratory. During this experiment, olivine was reacted with isotopically heavy water (δ18O 21.5‰) at T = 300 °C,  = 300 bar, for 100 days. The oxygen isotopic composition of the experimental serpentine was enriched in 18O (by 10 ‰ in δ18O) due to exchange of oxygen isotopes between olivine and the 18O‐rich water. Dehydrated serpentine was then produced during laboratory heating experiment in vacuum, at T = 930 °C, for 1 h. The oxygen isotopic composition of the dehydrated serpentine was enriched in 18O by a further 7 ‰. The net result of the hydration–dehydration process was an enrichment of 18O in the final material by approximately 17‰. The new experimental results suggest that the oxygen isotopic compositions of MCCs of the Belgica‐like group, including Dhofar 225 and Dhofar 725, could be derived from those of typical CM2 chondrites via several cycles of hydration–dehydration caused by aqueous alteration and subsequent thermal metamorphism within their parent asteroids.  相似文献   
72.
The authors thank the discusser for his interest and careful review of the paper and his valuable comments.They also welcome this discussion,because it gives the authors the opportunity to clarify several points which were not explained in sufficient detail in the paper,due to space limitations. The paper does not provide any personal or professional criticism of the discusser or his work and if any statement may have raised an ambiguous interpretation,this should be clarified and dismissed.Any inaccuracy in the reference's citation was not intentional.Some of the authors do not speak Italian;therefore they could not read directly and understand the paper cited by the discusser,which is in Italian.  相似文献   
73.
Balkas (large Quaternary gullies) of the south‐western part of the East European Plain (and their analogues in Central and Western Europe) are considered in terms of their geomorphology, lithology, sedimentology, modern surface processes, stratigraphy and palaeogeography. Features attributed to balkas in comparison with regular gullies and small river valleys are described. Balkas are widespread elements of the modern landscape with the same characteristic gentle‐concave bottom as regular gullies, and with or without weakly incised river channels. Buried gully incisions of different ages (post‐Gelasian) with the same shape are also revealed below modern Balkas. They are infilled by characteristic balka alluvial, slope and even lacustrine‐bog deposits, in places representing compound sequences of fluvial‐aeolian sedimentation. The fluvial part reflects multiple series of ephemeral episodes of increased water and sediment supply within temporary streams. Two conspicuous series supposedly fall within the final stages of the Dnieper (late Middle Pleistocene) and Valdai (Late Pleistocene) glaciations. Different ideas concerning the increase of surface runoff and erodibility of soils that might favour active balkas under conditions of land‐ice decay and permafrost, including its degradation, are discussed. The development of balkas included relatively short phases of incision and accumulation interrupted by much longer periods of inactivity, when they were subjected to surface processes in a subaerial environment or left as a relic. However, during active phases they served as important and powerful depositories and arteries of rill–gully–balka sedimentation systems, collecting and transmitting eroded material to the river valleys. These phases are related to climatic oscillations and were to some degree independent of fluvial processes affecting the permanent streams. Most of the Middle‐Late Pleistocene balkas retained their primary features, having subsequently been incorporated into the erosional network. In contrast, some of them were totally infilled and disappeared from the landscape. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
74.
75.
The dissolution and surface complexation of a non-stoichiometric hydroxyapatite (Ca8.4(HPO4)1.6(PO4)4.4(OH)0.4), (HAP) was studied in the pH range 3.5-10.5, at 25 °C in 0.1 M Na(Cl). The results from well-equilibrated batch experiments, potentiometric titrations, and zeta-potential measurements were combined with information provided by Attenuated Total Reflectance Fourier Transform Infrared (ATR-FTIR) spectroscopy and X-ray Photoelectron Spectroscopy (XPS). The information from the analyses was used to design an equilibration model that takes into account dissolution, surface potential, solution and surface complexation, as well as possible phase transformations. The results from the XPS measurements clearly show that the surface of the mineral has a different composition than the bulk and that the Ca/P ratio of the surface layer is 1.4 ± 0.1. This ratio was also found in solution in the batches equilibrated at low pH where the dominating reaction is dissolution. In the batches equilibrated at near neutral pH values, however, the Ca/P ratio in solution attains values as high as 25, which is due to re-adsorption of phosphate ions to the HAP surface. The total concentration of protons as well as the total concentration of dissolved calcium and phosphate in solution were used to calculate a model for the dissolution and surface complexation of HAP. The constant capacitance model was applied in designing the following surface complexation model:
  相似文献   
76.
Natural Hazards - Rockfalls represents a sudden, extremely important geomorphological hazard and may become a threat for people’s life, as well as goods and transport. The present study aims...  相似文献   
77.
Ground-based observations of faint satellites nearby their planets with 1-2 m class telescopes usually do not allow for high quality astrometry and photometry, due to saturation by the primary or to poor S/N ratio on the satellite images, generally embedded on the scattered light of the planet. Earth-based observations of the Uranus satellites’ upcoming mutual events in 2007-2008 are no exception. In most cases, the event will take place at 4 arcs or less from the planet, with “planet minus satellite” brightness differences of 10 magnitudes. So as to make feasible the observations of these important phenomena, we have developed a prototype of a coronagraph of simple design making use of good quality commercial optical systems. Pilot tests made with this coronagraph with a telescope of show that it is possible to obtain S/N ratios of 50 or higher for 10 s exposures, for satellites as close as 2 Uranus radii from the planet center. We have also developed numerical algorithms which perform digital coronagraphy in the images, with the elimination of the influence of the planets’ scattered light. This procedure considerably improves the S/N ratio of the satellite images (with or without a coronagraph instrument) and shall be applied in the reduction of the observations of the Uranus events so as to achieve the highest possible photometric and astrometric quality.  相似文献   
78.
Russian cities at a crossroads   总被引:1,自引:0,他引:1  
The research project `Changes in the Russian urban system after the dissolution of the Soviet Union' supported by the German Science and Research Society aims to reveal the impact of change in (1) the national and regional urban network, (2) the type and condition of Russian cities, and (3) the factors and actors affecting urban development. In this contribution the focus is made on the first task. The authors argue that visible stabilisation of the Russian urbanisation under crisis and/or under a new stage involves a good deal of restructuring and qualitative change. The hierarchy of the nation-wide functional centres is in flux. Within regions `alternative' foci attract industries, capital and people, and compete with regional capitals. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   
79.
The interaction of ash flows with ridges   总被引:1,自引:0,他引:1  
 Using both laboratory experiments and theoretical models, we examine the different flow regimes that may develop when an ash flow encounters a ridge. For very small ridges, all the flow may pass over the ridge. For intermediate-size ridges, the flow may be partially blocked, with a fraction of the flow reflected upstream as a travelling bore. In this case, the remainder of the flow, which does pass over the ridge, is hydraulically controlled at the ridge crest. Finally, if the ridge is sufficiently high, then the flow will be totally blocked. New laboratory experiments show that the sedimentation patterns associated with these flow regimes may be very different. Most importantly, flows that involve partial blocking and the formation of upstream propagating bores display enhanced sedimentation upstream of the ridge, analogous to valley-ponded and caldera-fill deposits. In contrast, under some circumstances, if the flow is able to scale a ridge, the deposit may be relatively unaffected by the presence of the ridge. The minimum ridge height that leads to total blocking of the flow increases with mass eruption rate and has a complex variation with distance from the source. In a one-dimensional channel, the minimum ridge height that causes blocking increases with distance downstream. This is because the flow becomes less dense through sedimentation of particles and entrainment of air and so requires less energy to scale a ridge of a particular height. In axisymmetric flow, the minimum ridge height initially decreases with distance downstream as the flow spreads radially, but subsequently increases as the flow becomes less dense through sedimentation and entrainment. A new quantitative model of dilute ash flows propagating over ridges indicates that flows with mass fluxes in excess of 108–109 kg/s can partially scale barriers as high as 1000 m at distances of tens of kilometres from the source, whereas smaller flows are likely to be totally blocked by such an obstacle. Our results shed new insight on the possible long-range transport mechanism of several large flows including the Ata, Fisher and Aniakchak pyroclastic flows. Received: 20 December 1996 / Accepted: 15 March 1998  相似文献   
80.
Modeling potential global redistribution of terrestrial vegetation frequently is based on bioclimatic classifications which relate static regional vegetation zones (biomes) to a set of static climate parameters. The equilibrium character of the relationships limits our confidence in their application to scenarios of rapidly changing climate. Such assessments could be improved if vegetation migration and succession would be incorporated as response variables in model simulations. We developed the model MOVE (Migration Of VEgetation), to simulate the geographical implications of different rates of plant extirpation and in-migration. We used the model to study the potential impact on terrestrial carbon stocks of climate shifts hypothesized from a doubling of atmospheric greenhouse gas concentration. The model indicates that the terrestrial vegetation and soil could release carbon; the amount of this carbon pulse depends on the rate of migration relative to the rate of climate change. New temperate and boreal biomes, not found on the landscape today, increase rapidly in area during the first 100 years of simulated response to climate change. Their presence for several centuries and their gradual disappearance after the climate ceases to change adds uncertainty in calculating future terrestrial carbon fluxes.  相似文献   
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